Solid-state physics
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Phases · Phase transition
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Solid-state physics, the largest branch of condensed matter physics, is the study of rigid matter, or solids, through methods such as quantum mechanics, crystallography, electromagnetism and metallurgy. Solid-state physics considers how the large-scale properties of solid materials result from their atomic-scale properties. Solid-state physics thus forms the theoretical basis of materials science, as well as having direct applications, for example in the technology of transistors and semiconductors.
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Introduction
Solid materials are formed from densely-packed atoms, with intense interaction forces between them. These interactions are responsible for the mechanical (e.g. hardness and elasticity), thermal, electrical, magnetic and optical properties of solids. Depending on the material involved and the conditions in which it was formed, the atoms may be arranged in a regular, geometric pattern (crystalline solids, which include metals and ordinary water ice) or irregularly (an amorphous solid such as common window glass).
The bulk of solid-state physics theory and research is focused on crystals, largely because the periodicity of atoms in a crystal — its defining characteristic — facilitates mathematical modeling, and also because crystalline materials often have electrical, magnetic, optical, or mechanical properties that can be exploited for engineering purposes.
The forces between the atoms in a crystal can take a variety of forms. For example, in a crystal of sodium chloride (common salt), the crystal is made up of ionic sodium and chlorine, and held together with ionic bonds. In others, the atoms share electrons and form covalent bonds. In metals, electrons are shared amongst the whole crystal in metallic bonding. Finally, the noble gases do not undergo any of these types of bonding. In solid form, the noble gases are held together with van der Waals forces resulting from the polarisation of the electronic charge cloud on each atom. The differences between the types of solid result from the differences between their bonding.
Crystal structure and properties
Many properties of materials are affected by their crystal structure. This structure can be investigated using a range of crystallographic techniques, including X-ray crystallography, neutron diffraction and electron diffraction.
The sizes of the individual crystals in a crystalline solid material vary depending on the material involved and the conditions when it was formed. Most crystalline materials encountered in everyday life are polycrystalline, with the individual crystals being microscopic in scale, but macroscopic single crystals can be produced either naturally (e.g. diamonds) or artificially.
Real crystals feature defects or irregularities in the ideal arrangements, and it is these defects that critically determine many of the electrical and mechanical properties of real materials.
The crystal lattice can vibrate. These vibrations are found to be quantised, the quantised vibrational modes being known as phonons. Phonons play a major role in many of the physical properties of solids, such as the transmission of sound. In insulating solids, phonons are also the primary mechanism by which heat conduction takes place. Phonons are also necessary for understanding the lattice heat capacity of a solid, as in the Einstein model and the later Debye model.
Electronic properties
Properties of materials such as electrical conduction and heat capacity are investigated by solid state physics. An early model of electrical conduction was the Drude model, which applied kinetic theory to the electrons in a solid. By assuming that the material contains immobile positive ions and an "electron gas" of classical, non-interacting electrons, the Drude model was able to explain electrical and thermal conductivity and the Hall effect in metals, although it greatly overestimated the electronic heat capacity.
Arnold Sommerfeld combined the classical Drude model with quantum mechanics in the free electron model (or Drude-Sommerfeld model). Here, the electrons are modelled as a Fermi gas, a gas of particles which obey the quantum mechanical Fermi-Dirac statistics. The free electron model gave improved predictions for the heat capacity of metals, however, it was unable to explain the existence of insulators.
The nearly-free electron model is a modification of the free electron model which includes a weak periodic perturbation meant to model the interaction between the conduction electrons and the ions in a crystalline solid. By introducing the idea of electronic bands, the theory explains the existence of [conductors], semiconductors and insulators.
The nearly-free electron model rewrites the Schrödinger equation for the case of a periodic potential. The solutions in this case are known as Bloch states. Since Bloch's theorem applies only to periodic potentials, and since unceasing random movements of atoms in a crystal disrupt periodicity, this use of Bloch's theorem is only an approximation, but it has proven to be a tremendously valuable approximation, without which most solid-state physics analysis would be intractable. Deviations from periodicity are treated by quantum mechanical perturbation theory.
Modern research in solid state physics
Current research topics in solid state physics include:
- Quasicrystals
- Spin glass
- Superconductivity
- Semiconductor device fabrication in the semiconductor industry
References
- Neil W. Ashcroft and N. David Mermin, Solid State Physics (Harcourt: Orlando, 1976).
- Charles Kittel, Introduction to Solid State Physics (Wiley: New York, 2004).
- H. M. Rosenberg, The Solid State (Oxford University Press: Oxford, 1995).
- Out of the Crystal Maze. Chapters from the History of Solid State Physics, ed. Lillian Hoddeson, Ernest Braun, Jürgen Teichmann, Spencer Weart (Oxford: Oxford University Press, 1992).
- M. A. Omar, Elementary Solid State Physics (Revised Printing, Addison Wesley, 1993).
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